I've used Eyeball Chat before in the past and it works pretty damned well. It also works through almost every network configuration I've used it on. Files that won't go through college ports due to firewalls can be sent using Eyeball Chat as well.
http://www.eyeballchat.com/
It's free and easy to use. It may not be the best, but it does what I wanted it to do.
-Lasereth
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"A Darwinian attacks his theory, seeking to find flaws. An ID believer defends his theory, seeking to conceal flaws." -Roger Ebert
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