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I used a heat gun to remove both silicone and latex caulk, but on a vinyl floor, I would NOT use a heat gun. It will end up ruining the vinyl floor.
When I was in Lowe's the other day, I saw that DAP made a "caulk remover" that was sold right alongside the caulk. I've never used the product, but for a couple of dollars, I would probably try that first.
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